Schematische Darstellung der neuartigen Synthese von metallorganischen Käfigverbindung, MOF (metal organic framework), durch abwechselndes Belegen einer organischen Oberfläche mit Kupferionen (MLx, Schritt 1) und COOH-funktionalisierten Liganden (L, Schritt 2). Ausgangspunkt ist eine organische, COOH-terminierte Oberfläche, die durch Adsorption eines entsprechenden Organothiols hergestellt wurde. Durch Wiederholen von Schritt 1 und Schritt 2 können beliebig dicke MOF-Schichten hergestellt werden.
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