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08/21/2024 14:17

Dormant Capacity Reserve in Lithium-Ion Batteries Detected

Philipp Jarke Kommunikation und Marketing
Technische Universität Graz

    Batteries undercut their theoretical capacity in practice, sometimes significantly. In a lithium iron phosphate cathode, researchers at TU Graz have now been able to observe exactly where the capacity loss occurs.

    Lithium iron phosphate is one of the most important materials for batteries in electric cars, stationary energy storage systems and tools. It has a long service life, is comparatively inexpensive and does not tend to spontaneously combust. Energy density is also making progress. However, experts are still puzzled as to why lithium iron phosphate batteries undercut their theoretical electricity storage capacity by up to 25 per cent in practice. In order to utilise this dormant capacity reserve, it would be crucial to know exactly where and how lithium ions are stored in and released from the battery material during the charging and discharging cycles. Researchers at Graz University of Technology (TU Graz) have now taken a significant step in this direction. Using transmission electron microscopes, they were able to systematically track the lithium ions as they travelled through the battery material, map their arrangement in the crystal lattice of an iron phosphate cathode with unprecedented resolution and precisely quantify their distribution in the crystal.

    Key clue for increasing the capacity of batteries further

    “Our investigations have shown that even when the test battery cells are fully charged, lithium ions remain in the crystal lattice of the cathode instead of migrating to the anode. These immobile ions incur a cost in capacity,” says Daniel Knez from the Institute of Electron Microscopy and Nanoanalysis at TU Graz. The immobile lithium ions are unevenly distributed in the cathode. The researchers have succeeded in precisely determining these areas of different levels of lithium enrichment and separating them from each other down to a few nanometres. Distortions and deformations were found in the crystal lattice of the cathode in the transition areas. “These details provide important information on physical effects that have so far counteracted battery efficiency and which we can take into account in the further development of the materials,” says Ilie Hanzu from the Institute of Chemistry and Technology of Materials, who was closely involved in the study.

    Methods also transferable to other battery materials

    For their investigations, the researchers prepared material samples from the electrodes of charged and discharged batteries and analysed them under the atomic-resolution ASTEM microscope at TU Graz. They combined electron energy loss spectroscopy with electron diffraction measurements and atomic-level imaging. “By combining different examination methods, we were able to determine where the lithium is positioned in the crystal channels and how it gets there,” explains Nikola Šimić from the Institute of Electron Microscopy and Nanoanalysis and first author of the paper on the results, which the research team recently published in the journal Advanced Energy Materials. “The methods we have developed and the knowledge we have gained about ion diffusion can be transferred to other battery materials with only minor adjustments in order to characterise them even more precisely and develop them further.”


    Contact for scientific information:

    Daniel KNEZ
    Dipl.-Ing. Dr.techn. BSc
    TU Graz | Institute of Electron Microscopy and Nanoanalysis
    Phone: +43 316 873 8831
    knez@tugraz.at

    Ilie HANZU
    Ass.Prof. Priv.-Doz. Dr.
    TU Graz | Institute for Chemistry and Technology of Materials
    Phone: +43 316 873 32329
    hanzu@tugraz.at


    Original publication:

    Phase Transitions and Ion Transport in Lithium Iron Phosphate by Atomic-Scale Analysis to Elucidate Insertion and Extraction Processes in Li-Ion Batteries
    In: Advanced Energy Materials; 2024, 2304381
    Authors: Nikola Šimić, Anna Jodlbauer, Michael Oberaigner, Manfred Nachtnebel, Stefan Mitsche, H. Martin R. Wilkening, Gerald Kothleitner, Werner Grogger, Daniel Knez, Ilie Hanzu
    DOI: https://doi.org/10.1002/aenm.202304381


    More information:

    https://www.tugraz.at/en/research/fields-of-expertise/advanced-materials-science... This research area is anchored in the Field of Expertise Advanced Materials Science, one of five strategic foci of TU Graz.


    Images

    Daniel Knez holds a sample of the battery material with tweezers. In the background (from left) Werner Grogger, Nikola Šimić, Anna Jodlbauer and Gerald Kothleitner.
    Daniel Knez holds a sample of the battery material with tweezers. In the background (from left) Wern ...
    Lunghammer - TU Graz
    Lunghammer - TU Graz

    High-resolution image of lithium-rich (bottom right) and lithium-poor (top left) areas of the sample material. For easier comparison, both areas are also shown in images of simulations.
    High-resolution image of lithium-rich (bottom right) and lithium-poor (top left) areas of the sample ...
    FELMI – TU Graz
    FELMI – TU Graz


    Criteria of this press release:
    Business and commerce, Journalists, Scientists and scholars
    Energy, Materials sciences, Physics / astronomy, Traffic / transport
    transregional, national
    Research results
    English


     

    Daniel Knez holds a sample of the battery material with tweezers. In the background (from left) Werner Grogger, Nikola Šimić, Anna Jodlbauer and Gerald Kothleitner.


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    High-resolution image of lithium-rich (bottom right) and lithium-poor (top left) areas of the sample material. For easier comparison, both areas are also shown in images of simulations.


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