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Two examples of the quantum mechanical wave functions for the atomic nuclei in H3+ at high excitation (corresponding to the 6th and 7th harmonics of the bending vibration in (a) and (b), respectively). They are taken from results of the new calculations (electronic supplement of the paper in Physical Review Letter). The square of this function yields the probability density of locating the atomic nuclei relative to each other. The wave functions show a high probability density for linear configurations of H3+, extremely far away from the equilateral triangular structure of non-vibrating H3+. With the new theory such configurations can be described exactly.
Graph: Authors of the paper
(164 KB, 540 x 807 pixels)
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