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“Core-shell” clusters pave the way for new efficient nanomaterials that make catalysts, magnetic and laser sensors or measuring devices for detecting electromagnetic radiation more efficient.
Whether in innovative high-tech materials, more powerful computer chips, pharmaceuticals or in the field of renewable energies, nanoparticles – smallest portions of bulk material – form the basis for a whole range of new technological developments. Due to the laws of quantum mechanics, such particles measuring only a few millionths of a millimetre can behave completely differently in terms of conductivity, optics or robustness than the same material on a macroscopic scale. In addition, nanoparticles or nanoclusters have a very large catalytically effective surface area compared to their volume. For many applications this allows material savings while maintaining the same performance.
Further development of top-level research in Graz in the field of nanomaterials
Researchers at the Institute of Experimental Physics (IEP) at Graz University of Technology have developed a method for assembling nanomaterials as desired. They let superfluid helium droplets of an internal temperature of 0.4 Kelvin (i.e. minus 273 degrees Celsius) fly through a vacuum chamber and selectively introduce individual atoms or molecules into these droplets. “There, they coalesce into a new aggregate and can be deposited on different substrates," explains experimental physicist Wolfgang Ernst from TU Graz. He has been working on this so-called helium-droplet synthesis for twenty-five years now, has successively developed it further during this time, and has produced continuous research at the highest international level, mostly performed in "Cluster Lab 3", which has been set up specifically for this purpose at the IEP.
Reinforcement of catalytic properties
In Nano Research, Ernst and his team now report on the targeted formation of so-called core-shell clusters using helium-droplet synthesis. The clusters have a 3-nanometer core of silver and a 1.5-nanometer-thick shell of zinc oxide. Zinc oxide is a semiconductor that is used, for example, in radiation detectors for measuring electromagnetic radiation or in photocatalysts for breaking down organic pollutants. The special thing about the material combination is that the silver core provides a plasmonic resonance, i.e. it absorbs light and thus causes a high light field amplification. This puts electrons in an excited state in the surrounding zinc oxide, thereby forming electron-hole pairs – small portions of energy that can be used elsewhere for chemical reactions, such as catalysis processes directly on the cluster surface. "The combination of the two material properties increases the efficiency of photocatalysts immensely. In addition, it would be conceivable to use such a material in water splitting for hydrogen production," says Ernst, naming a field of application.
Nanoparticles for laser and magnetic sensors
In addition to the silver-zinc oxide combination, the researchers produced other interesting core-shell clusters with a magnetic core of the elements iron, cobalt or nickel and a shell of gold. Gold also has a plasmonic effect and also protects the magnetic core from unwanted oxidation. These nanoclusters can be influenced and controlled both by lasers and by external magnetic fields and are suitable for sensor technologies, for example. For these material combinations, temperature-dependent stability measurements as well as theoretical calculations were carried out in collaboration with the IEP theory group led by Andreas Hauser and the team of Maria Pilar de Lara Castells (Institute of Fundamental Physics at the Spanish National Research Council CSIC, Madrid) and can explain the behaviour at phase transitions such as alloy formation that deviates from macroscopic material samples. The results were published in the Journal of Physical Chemistry.
Ernst now hopes that the findings from the experiments will be rapidly transferred into new catalysts "as soon as possible".
This research area is anchored in the Field of Expertise "Advanced Materials Science", one of five strategic foci of TU Graz. The Cluster 3 laboratory was set up using funds from the European Regional Development Fund (ERDF) with the support of the European Union and the State of Styria. The measurements for photoelectron spectroscopy of the particles could be carried out with the aid of a photoemission electron microscope in the framework of the structural funds of the higher education area of the Austrian Federal Government. The work was also supported by three projects of the Austrian Research Fund FWF.
Wolfgang ERNST
Em.Univ.-Prof. Dipl.-Phys. Dr.rer.nat.
Tel.: +43 316 873 8140; E-Mail: wolfgang.ernst@tugraz.at
Florian LACKNER
Univ.Ass. Dipl.-Ing. Dr.techn.
Tel.: +43 316 873 8647; E-Mail: florian.lackner@tugraz.at
Andreas HAUSER
Assoc.Prof. Mag. phil. Dipl.-Ing. Dr. phil Dr. techn.
Tel.: +43 316 873 8157; E-Mail: andreas.hauser@tugraz.at
At Institute of Fundamental Physics at the Spanish National Research Council CSIC, Madrid:
Maria Pilar de Lara Castells
E-Mail: Pilar.deLara.Castells@csic.es
Helium droplet assisted synthesis of plasmonic Ag@ZnO core@shell nanoparticles
Alexander Schiffmann, Thomas Jauk, Daniel Knez, Harald Fitzek, Ferdinand Hofer, Florian Lackner, Wolfgang E. Ernst
Nano Research
DOI: 10.1007/s12274-020-2961-z
Thermally Induced Diffusion and Restructuring of Iron Triade (Fe, Co, Ni) Nanoparticles Passivated by Several Layers of Gold
Martin Schnedlitz, Daniel Knez, Maximilian Lasserus, Ferdinand Hofer, Ricardo Fernández-Perea, Andreas W. Hauser, Marı́a Pilar de Lara-Castells, and Wolfgang E. Ernst
The Journal of Physical Chemistry
DOI: 10.1021/acs.jpcc.0c04561
https://www.tugraz.at/en/institutes/iep/home/ (Website Institute of Experimental Physics)
https://www.tugraz.at/en/research/fields-of-expertise/advanced-materials-science... (Field of Expertise "Advanced Materials Science")
https://www.fwf.ac.at/en/ (Austrian Research Fund FWF)
The graph illustrates the stepwise synthesis of Silver-Zinc Oxide core-shell clusters.
© IEP – TU Graz
© IEP – TU Graz
Together with his team, the experimental physicist Wolfgang Ernst of TU Graz succeeded in the target ...
http://lunghammer.at/
© Lunghammer – TU Graz
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The graph illustrates the stepwise synthesis of Silver-Zinc Oxide core-shell clusters.
© IEP – TU Graz
© IEP – TU Graz
Together with his team, the experimental physicist Wolfgang Ernst of TU Graz succeeded in the target ...
http://lunghammer.at/
© Lunghammer – TU Graz
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