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Scientists have observed the molecular motion of rubber components typically used in automobile tires—polybutadiene and carbon black—with the world’s fastest time resolution. The study reveals a clear interaction between the two components on the atomic scale, paving the way towards improved diagnostics of tire rubber degradation and the development of materials with enhanced durability.
Tire rubber is a composite material that typically includes synthetic rubber, such as polybutadiene, and added nanoparticles, such as carbon black, to improve its physical properties. During driving, strong forces act on the tire, causing its components to move against each another, which can lead to wear and degradation of the material. To evaluate tire performance, it is therefore important to understand not only the static structure of the complex particle network formed by the polymer and the nanoparticles, but also their interaction and respective movements, as these dynamics directly influence material properties such as wear resistance. Because some of these molecular movements happen extremely quickly, time-resolved measurements at atomic resolution on the fastest possible time scale are critical for developing and validating dynamic models of such materials.
An international research team led by scientists from the University of Tokyo, Ibaraki University, and European XFEL has now observed the molecular motion within samples of polybutadiene and carbon black, which occurs naturally as a result of the material structure, with a time resolution of 890 nanoseconds (billionths of a second)—the fastest resolution obtained in such studies so far—at the European XFEL’s SPB/SFX instrument.
“Using the recently developed method of diffracted X-ray blinking, we simultaneously detected fast changes in the polymer chains and in the additive nanoparticles on the atomic scale,” says Tokushi Sato from European XFEL, one of the corresponding authors of the publication. “We observed a clear interaction between polybutadiene and carbon black, indicating that the mobility of polybutadiene differed significantly depending on the type of carbon black added.” Each sample contained a different kind of carbon black. The experiment revealed that, in one sample, the polybutadiene moved much faster on the carbon black particle surface than in the other—resulting in poorer properties for automobile tire performance than the sample in which the two components were more strongly bound. The results may lead to improved methods to study tire rubber degradation in the laboratory during development and thus to devise materials with enhanced durability.
Alongside European XFEL, the study involved research institutions from Japan, Australia, and New Zealand as well as the Japanese company Sumitomo Rubber Industries.
About European XFEL:
European XFEL in the Hamburg area is an international research facility of superlatives: 27,000 X-ray flashes per second and a brilliance that is a billion times higher than that of the best conventional X-ray sources open up completely new opportunities for science. Research groups from around the world are able to map the atomic details of viruses, decipher the molecular composition of cells, take three-dimensional “photos” of the nanoworld, “film” chemical reactions, and study processes such as those occurring deep inside planets. The operation of the facility is entrusted to European XFEL, a non-profit company that cooperates closely with its main shareholder, the research centre DESY, and other organisations worldwide. European XFEL has a workforce of 500 employees and started user operation September 2017. At present, 12 countries have signed the European XFEL convention: Denmark, France, Germany, Hungary, Italy, Poland, Russia, Slovakia, Spain, Sweden, Switzerland, and the United Kingdom. For more information on European XFEL go to www.xfel.eu.
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