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With artificial photosynthesis, mankind could utilise solar energy to bind carbon dioxide and produce hydrogen. Chemists from Würzburg and Seoul have taken this one step further: They have synthesised a stack of dyes that comes very close to the photosynthetic apparatus of plants. It absorbs light energy, uses it to separate charge carriers and transfers them quickly and efficiently in the stack. The results are published in the journal ‘Nature Chemistry’.
Photosynthesis is a marvellous process: plants use it to produce sugar molecules and oxygen from the simple starting materials carbon dioxide and water. They draw the energy they need for this complex process from sunlight.
If humans could imitate photosynthesis, it would have many advantages. The free energy from the sun could be used to remove carbon dioxide from the atmosphere and use it to build carbohydrates and other useful substances. It would also be possible to produce hydrogen, as photosynthesis splits water into its components oxygen and hydrogen.
Photosynthesis: a Complex Process With Many Participants
So it's no wonder that many researchers are working on artificial photosynthesis. This is not easy, because photosynthesis is an extremely complex process: it takes place in the cells of plants in many individual steps and involves numerous dyes, proteins and other molecules. However, science is constantly making new advances.
One of the leading researchers in the field of artificial photosynthesis is chemist Professor Frank Würthner from Julius-Maximilians-Universität (JMU) Würzburg in Bavaria, Germany. His team has now succeeded in imitating one of the first steps of natural photosynthesis with a sophisticated arrangement of artificial dyes and analysing it more precisely.
The results were obtained in collaboration with Professor Dongho Kim's group at Yonsei University in Seoul (Korea). They have been published in the journal Nature Chemistry.
Fast and Efficient Energy Transport in a Stacking System
The researchers have succeeded in synthesising a stack of dyes that is very similar to the photosynthetic apparatus in plant cells – it absorbs light energy at one end, uses it to separate charge carriers and transfers them step by step to the other end via a transport of electrons. The structure consists of four stacked dye molecules from the perylene bisimide class.
‘We can specifically trigger the charge transport in this structure with light and have analysed it in detail. It is efficient and fast. This is an important step towards the development of artificial photosynthesis,’ says JMU PhD student Leander Ernst, who synthesised the stacked structure.
Supramolecular Wires as the Goal of the Research Work
Next, the JMU research team wants to expand the nanosystem of stacked dye molecules from four to more components – with the aim of ultimately creating a kind of supramolecular wire that absorbs light energy and transports it quickly and efficiently over longer distances. This would be a further step towards novel photofunctional materials that can be used for artificial photosynthesis.
Funding
The Bavarian Ministry of Science has funded the work as part of the ‘Solar Technologies go Hybrid’ (SolTech) research network. https://www.soltech-go-hybrid.de/
The work at Yonsei University in Seoul was funded by the National Research Foundation of Korea (NRF).
Prof. Dr Frank Würthner, Institute of Organic Chemistry, Center for Nanosystems Chemistry, University of Würzburg, frank.wuerthner@uni-wuerzburg.de
Photoinduced stepwise charge hopping in π-stacked perylene bisimide donor-bridge-acceptor arrays. Leander Ernst, Hongwei Song, Dongho Kim, Frank Würthner. Nature Chemistry, 14 March 2025, DOI 10.1038/s41557-025-01770-7
This is what the stack of four dyes synthesised in Würzburg looks like. It represents a further step ...
Leander Ernst
University of Wuerzburg
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This is what the stack of four dyes synthesised in Würzburg looks like. It represents a further step ...
Leander Ernst
University of Wuerzburg
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