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Chirality is a fundamental property of matter that determines many biological, chemical and physical phenomena. Chiral properties are however established when the material is grown, that is, the left- and right-handed enantiomers cannot be converted into one another without melting and recrystallization. Researchers at the MPI for the Structure and Dynamics of Matter (MPSD) and the University of Oxford have shown that terahertz light can induce chirality in a non-chiral crystal, allowing either left- or right-handed enantiomers to emerge on demand. The finding, reported in Science, opens up exciting possibilities for exploring novel non-equilibrium phenomena in complex materials.
Chirality is a fundamental property of matter that determines many biological, chemical and physical phenomena. Chiral solids, for example, offer exciting opportunities for catalysis, sensing and optical devices by enabling unique interactions with chiral molecules and polarized light. These properties are however established when the material is grown, that is, the left- and right-handed enantiomers cannot be converted into one another without melting and recrystallization. Researchers at the Max Planck Institute for the Structure and Dynamics of Matter (MPSD) and the University of Oxford have shown that terahertz light can induce chirality in a non-chiral crystal, allowing either left- or right-handed enantiomers to emerge on demand. The finding, reported in Science, opens up exciting possibilities for exploring novel non-equilibrium phenomena in complex materials.
Chirality refers to objects that cannot be superimposed to their mirror images through any combination of rotations or translations, much like the distinct left and right hands of a human. In chiral crystals, the spatial arrangement of atoms confers a specific "handedness", which, for example, influences their optical and electrical properties.
The Hamburg-Oxford team focused on so-called antiferro-chirals, a type of non-chiral crystals reminiscent of antiferro-magnetic materials, in which magnetic moments anti-align in a staggered pattern leading to a vanishing net magnetization. An antiferro-chiral crystal is composed of equivalent amounts of left- and right-handed substructures in a unit cell, rendering it overall non-chiral.
The research team, led by Andrea Cavalleri, used terahertz light to lift this balance in the non-chiral material boron phosphate (BPO4), in this way inducing finite chirality on an ultrafast time scale. “We exploit a mechanism termed nonlinear phononics," says Zhiyang Zeng, lead author of this work. “By exciting a specific terahertz frequency vibrational mode, which displaces the crystal lattice along the coordinates of other modes in the material, we created a chiral state that survives for several picoseconds,” he added. “Notably, by rotating the polarization of the terahertz light by 90 degrees, we could selectively induce either a left- or right-handed chiral structure,” continues fellow author Michael Först.
"This discovery opens up new possibilities for the dynamical control of matter at the atomic level," says Andrea Cavalleri, group leader at the MPSD. "We are excited to see potential applications of this technology and how it can be used to create unique functionalities. The ability to induce chirality in non-chiral materials could lead to new applications in ultrafast memory devices or even more sophisticated optoelectronic platforms"
This work received financial support from the Deutsche Forschungsgemeinschaft via the Cluster of Excellence ‘CUI: Advanced Imaging of Matter’. The MPSD is a member of the Center for Free-Electron Laser Science (CFEL), a joint enterprise with DESY and the University of Hamburg.
Prof. Andrea Cavalleri
Phone: +49 (0)40 8998 88101
Email: andrea.cavalleri@mpsd.mpg.de
Priv.Doz. Michael Först
Phone: +49-40-8998-88105
michael.foerst@mpsd.mpg.de
Condensed Matter Department,
Max Planck Institute for the Structure and Dynamics of Matter
Center for Free-Electron Laser Science (CFEL)
Geb. 900 (MPSD)
Luruper Chaussee 149
22761 Hamburg / Germany
Photo-induced chirality in a nonchiral crystal
Z. Zeng, M. Först, M. Fechner, M. Buzzi, E. Amuah, C. Putzke, P.J.W. Moll, D. Prabhakaran, P. Radaelli, A. Cavalleri
Science 387, 431–436 (2025)
https://doi.org/10.1126/science.adr4713
Terahertz light has the ability to control solids at the atomic level, forming chiral structures of ...
Zhiyang Zeng (MPSD)
Zhiyang Zeng (MPSD)
Terahertz light has the ability to control solids at the atomic level, forming chiral structures of ...
Zhiyang Zeng (MPSD)
Zhiyang Zeng (MPSD)
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