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As industries seek innovative solutions for carbon capture, scientists have turned to advanced materials that efficiently trap and store carbon dioxide (CO₂) from industrial emissions. A recent study of a team from the Helmholtz-Zentrum Dresden-Rossendorf (HZDR), Dresden University of Technology (TUD), and Maria Curie-Skłodowska University in Lublin (Poland) sheds light on the gas adsorption physics of so-called Calgary Framework 20 (CALF-20), a zinc-based metal-organic framework (MOF). The research highlights how CALF-20 efficiently captures CO₂ while resisting interference from water – a common issue in carbon capture materials.
CO₂ capture technologies rely on materials that can selectively trap the greenhouse gas from gas streams while minimizing energy consumption. Traditional adsorbents, such as activated carbons and zeolites, often suffer from high-energy demands or poor selectivity in humid environments. In contrast, CALF-20 stands out due to its high CO₂ uptake and its mild heat of adsorption and regeneration. It maintains a high selectivity by preferentially adsorbing CO₂ over water in moderately humid conditions. CALF-20 captures CO₂ more effectively and absorbs less water in such conditions, when compared to other widely studied similar compounds. All those MOFs are highly porous and made of metal-oxygen clusters, which are connected in a structured manner by pillars of organic chemicals. This three-dimensional arrangement leads to networks of cavities reminiscent of the pores of a kitchen sponge.
“In this study, we employed a multifaceted approach to investigate CALF-20’s CO₂ adsorption behavior. Using a combination of positron annihilation lifetime spectroscopy (PALS), in situ powder X-ray diffraction (PXRD), as well as gas adsorption experiments, we were able to visualize the interaction between CO₂ molecules and the material’s internal structure under different temperatures and humidity levels. These insights provide important information for optimizing CO₂ capture technologies in real-world industrial settings”, explains Dr. Ahmed Attallah from the Institute of Radiation Physics at HZDR.
A deep dive into adsorption mechanisms
“PALS plays a critical role in analyzing how gases interact with porous materials. This technique measures the lifetime of positronium, a bound state of an electron and a positron, which is sensitive to local free volumes. In porous materials like CALF-20, positronium lifetimes indicate empty spaces, their size, and how they change when gas molecules start to fill the pores”, Prof. Radosław Zaleski from the Maria Curie-Skłodowska University Lublin says.
Through PALS, researchers observed that CO₂ initially gathers at the center of CALF-20’s nanopores, forming a structured arrangement before adhering to the pore walls. This progression correlates with increasing CO₂ pressure, confirming that PALS can track molecular adsorption steps in real time. The method also revealed that even after CO₂ fills the pores, small free volumes persist, which may be critical for enhancing adsorption efficiency.
PALS was particularly useful in distinguishing how CO₂ and water interact within the material. Under humid conditions, PALS data showed that water forms isolated clusters at low humidity, but at higher humidity levels, it forms interconnected networks. “These structural changes affect pore accessibility, yet CALF-20 maintains its significant CO₂ adsorption capacity at a relative humidity below 40 per cent. Conventional gas adsorption methods alone would struggle to resolve these fine structural variations, demonstrating the unique value of PALS in analyzing dynamic gas-material interactions”, TUD’s Prof. Stefan Kaskel resumes.
The impact of humidity: A key challenge in CO₂ capture
In industrial applications, CO₂ is rarely captured from dry gas streams – moisture is almost always present. This poses a challenge for many materials, as water molecules often compete with CO₂ for adsorption sites, reducing efficiency.
Through in situ humidity-controlled experiments, the team discovered that CALF-20 maintains a robust CO₂ adsorption performance even in the presence of water, where the level of relative humidity defines this robustness. At low humidity, water molecules remain isolated within the framework. This network formation alters the material’s free volume, but CO₂ still finds available adsorption sites, demonstrating CALF-20’s resilience under humid conditions. At increasingly higher humidity levels, they form interconnected hydrogen-bonded networks, allowing water uptake to dominate.
By integrating PALS with other characterization techniques, this study provides a comprehensive understanding of how CALF-20 captures CO₂ under diverse environmental conditions. The results suggest that CALF-20 could serve as a scalable and energy-efficient solution for industrial CO₂ capture, particularly in settings where humidity poses a challenge. Developed by researchers at the University of Calgary, CALF-20 has already been scaled up to multi-kilogram production, making it a strong candidate for real-world applications
The implications extend beyond fundamental science – these insights could pave the way for optimizing next-generation MOFs for large-scale deployment in carbon capture and storage (CCS) applications. Further research will focus on long-term stability and process integration, moving closer to the implementation of CALF-20 in industrial CO₂ mitigation strategies.
The study was supported by DFG (Deutsche Forschungsgemeinschaft) under contract 464857745 (AT 289/1-1 and KA1698/41-1).
Publication:
A. G. Attallah, V. Bon, E. Hirschmann, M. Butterling, A. Wagner, R. Zaleski, S. Kaskel, Uncovering the dynamic CO2 gas uptake behavior of CALF-20 (Zn) under varying conditions via positronium lifetime analysis, in Small, 2025 (DOI: 10.1002/smll.202500544)
More information:
Dr. Ahmed Gamal Attallah Elsherif
Institute of Radiation Physics at HZDR
Phone: +49 351 260 2323 | Email: a.elsherif@hzdr.de
Prof. Stefan Kaskel
Chair of Inorganic Chemistry
Dresden University of Technology
Phone: +49 351 463 4567 | Email: stefan.kaskel@tu-dresden.de
Prof. Radosław Zaleski
Institute of Physics | Maria Curie-Skłodowska University Lublin
Phone: +48 81 537 61 45 | Email: radek@zaleski.umcs.pl
Media contact:
Simon Schmitt | Head
Communications and Media Relations at HZDR
Phone: +49 351 260 3400 | Mob.: +49 175 874 2865 | Email: s.schmitt@hzdr.de
The Helmholtz-Zentrum Dresden-Rossendorf (HZDR) performs – as an independent German research center – research in the fields of energy, health, and matter. We focus on answering the following questions:
• How can energy and resources be utilized in an efficient, safe, and sustainable way?
• How can malignant tumors be more precisely visualized, characterized, and more effectively treated?
• How do matter and materials behave under the influence of strong fields and in smallest dimensions?
To help answer these research questions, HZDR operates large-scale facilities, which are also used by visiting researchers: the Ion Beam Center, the Dresden High Magnetic Field Laboratory and the ELBE Center for High-Power Radiation Sources.
HZDR is a member of the Helmholtz Association and has six sites (Dresden, Freiberg, Görlitz, Grenoble, Leipzig, Schenefeld near Hamburg) with almost 1,500 members of staff, of whom about 680 are scientists, including 200 Ph.D. candidates.
Dr. Ahmed Gamal Attallah Elsherif
Institute of Radiation Physics at HZDR
Phone: +49 351 260 2323 | Email: a.elsherif@hzdr.de
Prof. Stefan Kaskel
Chair of Inorganic Chemistry
Dresden University of Technology
Phone: +49 351 463 4567 | Email: stefan.kaskel@tu-dresden.de
Prof. Radosław Zaleski
Institute of Physics | Maria Curie-Skłodowska University Lublin
Phone: +48 81 537 61 45 | Email: radek@zaleski.umcs.pl
A. G. Attallah, V. Bon, E. Hirschmann, M. Butterling, A. Wagner, R. Zaleski, S. Kaskel, Uncovering the dynamic CO2 gas uptake behavior of CALF-20 (Zn) under varying conditions via positronium lifetime analysis, in Small, 2025 (DOI: 10.1002/smll.202500544)
https://www.hzdr.de/presse/co2_mof
Artistic representation of CO2 capture from a moisture-laden gas stream using CALF-20, a zinc-based ...
B. Schröder
B. Schröder/HZDR
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